MOLECULAR POLARITY / 01
What makes a molecule polar?
A molecule is polar when its electric charge is distributed unevenly, giving it a net dipole moment. Both the bonds and their three-dimensional arrangement matter.
Two questions to ask
Are any bonds polar? Atoms with different electronegativities pull shared electrons unequally. Do those bond dipoles cancel? A bent or otherwise asymmetric arrangement often leaves a net dipole.
Water is a useful example: oxygen pulls electron density through two O–H bonds, and the bent H₂O structure prevents those bond dipoles from canceling. A straight line alone is not proof of nonpolarity: HCl is polar because its two atoms are different.
Explore H₂O in 3D ↗EXPLORE THE EXAMPLES
Polar molecules
AsH3Arsine↗BrF3Bromine Trifluoride↗BrF5Bromine Pentafluoride↗C2H2Cl2cis-1,2-Dichloroethene↗C2H3ClVinyl Chloride↗C2H3ClOAcetyl Chloride↗C2H4Br21,2-Dibromoethane↗C2H4Cl21,1-Dichloroethane↗C2H4Cl21,2-Dichloroethane↗C2H4OEthylene Oxide↗C2H4O2Methyl Formate↗C2H5BrBromoethane↗C2H5ClChloroethane↗C2H5FFluoroethane↗C2H5IIodoethane↗C2H5NOAcetamide↗C2H5NO2Glycine↗C2H5OHEthanol↗C2H6SDimethyl Sulfide↗C2H6SEthanethiol↗C2H7NDimethylamine↗C2H7NEthylamine↗C3H6OPropanal↗C3H6O2Ethyl Formate↗C3H6O2Propionic Acid↗C3H6O2Methyl Acetate↗C3H6O3Lactic Acid↗C3H8O1-Propanol↗C3H8OMethoxyethane↗C3H8OIsopropanol↗C3H8O3Glycerol↗C3H9NTrimethylamine↗C4H4OFuran↗C4H4SThiophene↗C4H6O3Acetic Anhydride↗C4H8OButanone↗C4H8O2Butyric Acid↗C4H8O2Ethyl Acetate↗C4H10O1-Butanol↗C4H10ODiethyl Ether↗C5H5NPyridine↗C6H5BrBromobenzene↗C6H5ClChlorobenzene↗C6H5FFluorobenzene↗C6H5NO2Nitrobenzene↗C6H6OPhenol↗C6H7NAniline↗C6H8O7Citric Acid↗C6H12O6D-Fructose↗C6H12O6D-Glucose↗C7H5NBenzonitrile↗C7H6OBenzaldehyde↗C7H6O3Salicylic Acid↗C7H8OBenzyl Alcohol↗C8H8OAcetophenone↗C8H10N4O2Caffeine↗C9H8O4Aspirin (Acetylsalicylic Acid)↗CCl2F2Dichlorodifluoromethane↗CClF3Chlorotrifluoromethane↗CH2Cl2Dichloromethane↗CH2F2Difluoromethane↗CH2OFormaldehyde↗CH3BrBromomethane↗CH3CHOAcetaldehyde↗CH3ClChloromethane↗CH3CNAcetonitrile↗CH3COCH3Acetone↗CH3COOHAcetic Acid↗CH3FFluoromethane↗CH3IIodomethane↗CH3NH2Methylamine↗CH3NO2Nitromethane↗CH3OCH3Dimethyl Ether↗CH3OHMethanol↗CH3SOCH3Dimethyl Sulfoxide↗CH4SMethanethiol↗CHCl3Chloroform↗CHClF2Chlorodifluoromethane↗CHF3Trifluoromethane↗Cl2ODichlorine Monoxide↗ClF3Chlorine Trifluoride↗COCarbon Monoxide↗COCl2Phosgene↗COF2Carbonyl Fluoride↗COSCarbonyl Sulfide↗H2CO3Carbonic Acid↗H2OWater↗H2O2Hydrogen Peroxide↗H2SHydrogen Sulfide↗H2SeHydrogen Selenide↗H2SO4Sulfuric Acid↗H3PO4Phosphoric Acid↗HBrHydrogen Bromide↗HClHydrogen Chloride↗HCNHydrogen Cyanide↗HCONH2Formamide↗HCOOHFormic Acid↗HFHydrogen Fluoride↗HIHydrogen Iodide↗HNO2Nitrous Acid↗HNO3Nitric Acid↗HOCH2CH2OHEthylene Glycol↗HOClHypochlorous Acid↗IClIodine Monochloride↗N2H4Hydrazine↗N2ONitrous Oxide↗NCl3Nitrogen Trichloride↗NF3Nitrogen Trifluoride↗NH2ClMonochloramine↗NH2CONH2Urea↗NH2OHHydroxylamine↗NH3Ammonia↗NONitric Oxide↗NO2Nitrogen Dioxide↗NOClNitrosyl Chloride↗NOFNitrosyl Fluoride↗O3Ozone↗OF2Oxygen Difluoride↗PBr3Phosphorus Tribromide↗PCl3Phosphorus Trichloride↗PF3Phosphorus Trifluoride↗PH3Phosphine↗SCl2Sulfur Dichloride↗SF2Sulfur Difluoride↗SF4Sulfur Tetrafluoride↗SO2Sulfur Dioxide↗SO2Cl2Sulfuryl Chloride↗SO2F2Sulfuryl Fluoride↗SOCl2Thionyl Chloride↗SOF2Thionyl Fluoride↗
Further reading: OpenStax Chemistry 2e, section 7.6.