MOLECULAR POLARITYFIELD NOTE 84 / 175

Is CH3SOCH3 polar or nonpolar?

CH3SOCH3 is polar because its sulfur–oxygen bond creates a strong dipole that the two methyl groups cannot cancel.

THE ANSWERPolar.

Dimethyl Sulfoxide · pyramidal around S; tetrahedral at each C

FIGURE 01

The molecule in space

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STRUCTURE / 01
S ×1O ×1C ×2H ×6
SHHHHCCOHH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why CH3SOCH3 is polar

Sulfur connects to two methyl carbons and oxygen, with a lone-pair contribution at the sulfur center. The S–O region is much more electron-rich than the methyl side, leaving a substantial net dipole.

A USEFUL DISTINCTION

What to notice

DMSO has two identical CH3 groups, but the oxygen occupies a different direction. This partial symmetry does not erase the S–O polarization.

QUICK REFERENCE

Common questions about CH3SOCH3

  1. 01
    What does the Lewis structure of CH3SOCH3 show?

    A common Lewis sketch is CH3–S(=O)–CH3 with a lone pair on S. Charge-separated resonance forms also describe the S–O bond.

  2. 02
    What is the molecular geometry of CH3SOCH3?

    CH3SOCH3 has a pyramidal around S; tetrahedral at each C molecular geometry. The 3D model shows representative bond angles of 107.5° and 95.8° and 108.6°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of CH3SOCH3?

    CH3SOCH3 has an approximate molar mass of 78.13 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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