MOLECULAR POLARITYFIELD NOTE 38 / 175

Is C4H4O polar or nonpolar?

Furan (C4H4O) is polar because an oxygen atom occupies one vertex of the ring and breaks all-carbon symmetry.

THE ANSWERPolar.

Furan · planar five-membered aromatic ring

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
O ×1C ×4H ×4
COCCCHHHH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why C4H4O is polar

Furan is a five-membered aromatic ring with four CH positions and one oxygen. The oxygen-bearing side differs from the hydrocarbon side, giving the ring a net dipole.

A USEFUL DISTINCTION

What to notice

One oxygen lone pair participates in aromatic delocalization while the other is in the ring plane; the simple ring sketch does not show all electron behavior.

QUICK REFERENCE

Common questions about C4H4O

  1. 01
    What does the Lewis structure of C4H4O show?

    The ring is O–CH=CH–CH=CH– in a closed cycle. Oxygen has two lone pairs, with one contributing to aromaticity.

  2. 02
    What is the molecular geometry of C4H4O?

    C4H4O has a planar five-membered aromatic ring molecular geometry. The 3D model shows representative bond angles of 106.6° and 106.1° and 127.6°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of C4H4O?

    C4H4O has an approximate molar mass of 68.07 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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