MOLECULAR POLARITYFIELD NOTE 88 / 175

Is CHF3 polar or nonpolar?

CHF3 is polar because three fluorines and one hydrogen give its tetrahedral carbon unequal ends.

THE ANSWERPolar.

Trifluoromethane · tetrahedral at C

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
F ×3C ×1H ×1
HCFFF
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why CHF3 is polar

The three C–F bonds are alike, but the fourth direction is a C–H bond. Their vector sum cannot cancel as it does in CF4, because hydrogen and fluorine make different bond dipoles.

A USEFUL DISTINCTION

What to notice

Compare CHF3 with CF4: replacing just one F by H turns a four-way symmetric nonpolar arrangement into a polar one.

QUICK REFERENCE

Common questions about CHF3

  1. 01
    What does the Lewis structure of CHF3 show?

    Carbon forms three C–F single bonds and one C–H single bond. Each fluorine has three lone pairs.

  2. 02
    What is the molecular geometry of CHF3?

    CHF3 has a tetrahedral at C molecular geometry. The 3D model shows representative bond angles of 107.9° and 111°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of CHF3?

    CHF3 has an approximate molar mass of 70.01 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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