MOLECULAR POLARITYFIELD NOTE 03 / 175

Is 1,2-Dichloroethane (C2H4Cl2) polar or nonpolar?

1,2-Dichloroethane (C2H4Cl2) is polar because its two C–Cl bonds can reinforce in accessible conformations.

THE ANSWERPolar.

1,2-Dichloroethane · tetrahedral at both C; flexible chain

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
Cl ×2C ×2H ×4
HCClHHClCH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why C2H4Cl2 is polar

Each carbon in 1,2-dichloroethane bears one chlorine. Rotation about the C–C single bond changes the instantaneous alignment of the two C–Cl bond dipoles, and the conformers are not all equally populated.

A USEFUL DISTINCTION

What to notice

A perfectly opposite pair of bond dipoles in one frozen conformer is not the whole molecular story; conformer populations matter for flexible 1,2-dichloroethane.

QUICK REFERENCE

Common questions about 1,2-Dichloroethane (C2H4Cl2)

  1. 01
    What does the Lewis structure of 1,2-Dichloroethane (C2H4Cl2) show?

    The connectivity is Cl–CH2–CH2–Cl. All heavy-atom bonds are single; each chlorine carries three lone pairs.

  2. 02
    What is the molecular geometry of 1,2-Dichloroethane (C2H4Cl2)?

    1,2-Dichloroethane (C2H4Cl2) has a tetrahedral at both C; flexible chain molecular geometry. The 3D model shows representative bond angles of 111.8° and 107.7° and 111.2°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of 1,2-Dichloroethane (C2H4Cl2)?

    C2H4Cl2 has an approximate molar mass of 98.95 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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