MOLECULAR POLARITYFIELD NOTE 137 / 175

Is NF3 polar or nonpolar?

NF3 is weakly polar because its three N–F bonds form a pyramidal arrangement and do not fully cancel.

THE ANSWERPolar.

Nitrogen Trifluoride · trigonal pyramidal

FIGURE 01

The molecule in space

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STRUCTURE / 01
F ×3N ×1
NFFF
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why NF3 is polar

NF3 has a trigonal pyramidal shape with a lone pair on nitrogen. Fluorine (3.98) is so much more electronegative than nitrogen (3.04) that the F atoms pull electrons outward, opposing the inward lone-pair dipole.

A USEFUL DISTINCTION

What to notice

NF3 and NH3 are both pyramidal and polar, but their bond dipoles point differently relative to the lone-pair contribution. NF3's net dipole is smaller.

QUICK REFERENCE

Common questions about NF3

  1. 01
    What does the Lewis structure of NF3 show?

    N makes three single N–F bonds and keeps one lone pair. Each F has three lone pairs.

  2. 02
    What is the molecular geometry of NF3?

    NF3 has a trigonal pyramidal molecular geometry. The 3D model shows representative bond angles of 110.4°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of NF3?

    NF3 has an approximate molar mass of 71.00 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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