MOLECULAR POLARITYFIELD NOTE 124 / 175

Is HNO2 polar or nonpolar?

Nitrous Acid (HNO2) is polar because its H–O–N=O connectivity has unlike ends and cannot cancel its bond dipoles.

THE ANSWERPolar.

Nitrous Acid · bent at N

FIGURE 01

The molecule in space

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STRUCTURE / 01
O ×2N ×1H ×1
OONH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why HNO2 is polar

Nitrous acid contains an O–H group attached through oxygen to nitrogen and a second, doubly bonded oxygen. Its N-centered arrangement and different terminal groups produce a net dipole.

A USEFUL DISTINCTION

What to notice

HNO2 is nitrous acid, whereas HNO3 is nitric acid. One extra oxygen changes the Lewis connectivity and the acid's chemistry.

QUICK REFERENCE

Common questions about HNO2

  1. 01
    What does the Lewis structure of HNO2 show?

    A useful neutral Lewis structure is H–O–N=O; nitrogen has one lone pair, the hydroxyl oxygen has two, and the terminal oxygen has two.

  2. 02
    What is the molecular geometry of HNO2?

    HNO2 has a bent at N molecular geometry. The 3D model shows representative bond angles of 101.6° and 111°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of HNO2?

    HNO2 has an approximate molar mass of 47.01 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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