MOLECULAR POLARITYFIELD NOTE 71 / 175

Is CH2O polar or nonpolar?

CH2O is polar because its strong C=O bond dipole is not canceled by the two C–H bonds in its planar structure.

THE ANSWERPolar.

Formaldehyde · trigonal planar

FIGURE 01

The molecule in space

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STRUCTURE / 01
O ×1C ×1H ×2
HOCH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why CH2O is polar

Formaldehyde has a trigonal planar geometry with a central carbon double-bonded to oxygen and single-bonded to two hydrogens. Oxygen (3.44) is much more electronegative than carbon (2.55), creating a strong C=O bond dipole.

A USEFUL DISTINCTION

What to notice

Formaldehyde is planar, yet it is polar: the C=O bond is unlike the two C–H bonds, so their contributions cannot balance it.

QUICK REFERENCE

Common questions about CH2O

  1. 01
    What does the Lewis structure of CH2O show?

    The common Lewis structure is H2C=O: carbon has two C–H single bonds and a C=O double bond. O has two lone pairs.

  2. 02
    What is the molecular geometry of CH2O?

    CH2O has a trigonal planar molecular geometry. The 3D model shows representative bond angles of 122.2° and 115.5°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of CH2O?

    CH2O has an approximate molar mass of 30.03 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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