MOLECULAR POLARITYFIELD NOTE 98 / 175

Is COS polar or nonpolar?

COS is polar because its straight O=C=S structure has different atoms at the two ends.

THE ANSWERPolar.

Carbonyl Sulfide · linear

FIGURE 01

The molecule in space

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STRUCTURE / 01
S ×1O ×1C ×1
SOC
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why COS is polar

The molecule is linear, but the C=O and C=S bonds are not equal dipoles because oxygen and sulfur differ. The two ends cannot cancel as equal opposite bonds do in CO2 or CS2.

A USEFUL DISTINCTION

What to notice

COS sits between the familiar CO2 and CS2 examples: all three are linear, yet only the mixed O/S termini leave a net molecular dipole.

QUICK REFERENCE

Common questions about COS

  1. 01
    What does the Lewis structure of COS show?

    The common connectivity is O=C=S, with a double bond to each terminal atom. O and S each have two lone pairs.

  2. 02
    What is the molecular geometry of COS?

    COS has a linear molecular geometry. The 3D model shows representative bond angles of 180°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of COS?

    COS has an approximate molar mass of 60.07 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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