MOLECULAR POLARITYFIELD NOTE 46 / 175

Is C5H5N polar or nonpolar?

Pyridine (C5H5N) is polar because one ring carbon is replaced by nitrogen, breaking benzene's charge symmetry.

THE ANSWERPolar.

Pyridine · planar six-membered aromatic ring

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
N ×1C ×5H ×5
CHHHNCCCHCH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why C5H5N is polar

Pyridine is an aromatic six-membered ring containing one nitrogen. Nitrogen's higher electronegativity creates a distinct ring position and a net molecular dipole.

A USEFUL DISTINCTION

What to notice

The nitrogen lone pair points outside the aromatic pi system; pyridine can accept a proton without becoming a different carbon framework.

QUICK REFERENCE

Common questions about C5H5N

  1. 01
    What does the Lewis structure of C5H5N show?

    A six-membered aromatic ring contains five CH positions and one N. Nitrogen has one lone pair; alternating-bond drawings are resonance contributors.

  2. 02
    What is the molecular geometry of C5H5N?

    C5H5N has a planar six-membered aromatic ring molecular geometry. The 3D model shows representative bond angles of 116.4° and 119.7° and 120.1°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of C5H5N?

    C5H5N has an approximate molar mass of 79.10 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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