MOLECULAR POLARITYFIELD NOTE 110 / 175

Is H2CO3 polar or nonpolar?

Carbonic Acid (H2CO3) is polar because its carbonyl oxygen differs from the two hydroxyl groups.

THE ANSWERPolar.

Carbonic Acid · trigonal planar around C

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
O ×3C ×1H ×2
COOOHH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why H2CO3 is polar

Carbonic acid has a central trigonal-planar carbon bonded to one carbonyl oxygen and two O–H oxygens. The three C–O directions are not chemically identical, leaving a molecular dipole.

A USEFUL DISTINCTION

What to notice

Do not apply the symmetry of carbonate CO3²− to neutral carbonic acid. In water, H2CO3 participates in an equilibrium with dissolved CO2 and bicarbonate.

QUICK REFERENCE

Common questions about H2CO3

  1. 01
    What does the Lewis structure of H2CO3 show?

    The neutral Lewis connectivity is HO–C(=O)–OH. Carbon has four bond-order units; each oxygen carries lone pairs.

  2. 02
    What is the molecular geometry of H2CO3?

    H2CO3 has a trigonal planar around C molecular geometry. The 3D model shows representative bond angles of 112° and 109.6°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of H2CO3?

    H2CO3 has an approximate molar mass of 62.02 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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