MOLECULAR POLARITYFIELD NOTE 70 / 175

Is CH2F2 polar or nonpolar?

CH2F2 is polar because two C–F bonds and two C–H bonds do not cancel around a tetrahedral carbon.

THE ANSWERPolar.

Difluoromethane · tetrahedral at C

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
F ×2C ×1H ×2
HFFCH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why CH2F2 is polar

The two fluorines draw electron density more strongly than the two hydrogens. A tetrahedron with two F and two H substituents is not a four-way equal-bond arrangement, so the C–F dipoles leave a nonzero resultant.

A USEFUL DISTINCTION

What to notice

Do not treat two fluorines as automatically opposite: in a tetrahedron any two bonds meet at roughly 109.5°, not 180°.

QUICK REFERENCE

Common questions about CH2F2

  1. 01
    What does the Lewis structure of CH2F2 show?

    Carbon makes four single bonds: two C–F and two C–H. Each fluorine has three lone pairs.

  2. 02
    What is the molecular geometry of CH2F2?

    CH2F2 has a tetrahedral at C molecular geometry. The 3D model shows representative bond angles of 107.1° and 109.5° and 111.5°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of CH2F2?

    CH2F2 has an approximate molar mass of 52.02 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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