MOLECULAR POLARITYFIELD NOTE 116 / 175

Is H3PO4 polar or nonpolar?

Phosphoric Acid (H3PO4) is polar because one terminal oxygen and three O–H groups give phosphorus inequivalent oxygen substituents.

THE ANSWERPolar.

Phosphoric Acid · approximately tetrahedral around P

FIGURE 01

The molecule in space

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STRUCTURE / 01
P ×1O ×4H ×3
HOHOOPOH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why H3PO4 is polar

Phosphorus is attached to four oxygens in a tetrahedral neighborhood. Three oxygens carry hydrogen and the fourth is represented as P=O in a common Lewis drawing, so the bond contributions are asymmetric.

A USEFUL DISTINCTION

What to notice

Phosphoric acid and phosphate are different species. The neutral acid has three O–H bonds; phosphate PO4³− has none.

QUICK REFERENCE

Common questions about H3PO4

  1. 01
    What does the Lewis structure of H3PO4 show?

    A conventional neutral drawing is O=P(OH)3. The three hydrogens are bonded to oxygen, not phosphorus.

  2. 02
    What is the molecular geometry of H3PO4?

    H3PO4 has a approximately tetrahedral around P molecular geometry. The 3D model shows representative bond angles of 103.9° and 105.1° and 114.3°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of H3PO4?

    H3PO4 has an approximate molar mass of 97.99 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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