MOLECULAR POLARITYFIELD NOTE 134 / 175

Is N2H4 polar or nonpolar?

N2H4 is polar because its two locally pyramidal nitrogen centers form a non-planar molecule with a net dipole.

THE ANSWERPolar.

Hydrazine · pyramidal at each N

FIGURE 01

The molecule in space

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STRUCTURE / 01
N ×2H ×4
HHHNNH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why N2H4 is polar

Hydrazine consists of two NH2 groups connected by an N–N bond, with each nitrogen bearing a lone pair. Nitrogen (3.04) is more electronegative than hydrogen (2.20).

A USEFUL DISTINCTION

What to notice

Each nitrogen in hydrazine has its own local pyramidal environment. The non-planar arrangement of the two NH2 groups prevents a simple cancellation argument.

QUICK REFERENCE

Common questions about N2H4

  1. 01
    What does the Lewis structure of N2H4 show?

    The connectivity is H2N–NH2. Each N makes three single bonds and keeps one lone pair.

  2. 02
    What is the molecular geometry of N2H4?

    The arrangement around each nitrogen is pyramidal. The 3D model shows representative bond angles of 109.1° and 106.1° and 109.2°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of N2H4?

    N2H4 has an approximate molar mass of 32.05 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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