MOLECULAR POLARITYFIELD NOTE 77 / 175

Is CH3COOH polar or nonpolar?

CH3COOH is polar because its carboxyl group places two oxygens at one end of the molecule.

THE ANSWERPolar.

Acetic Acid · tetrahedral at methyl C; planar at carboxyl C

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
O ×2C ×2H ×4
HHOOCCHH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why CH3COOH is polar

The –COOH group contains a carbonyl oxygen and a hydroxyl oxygen, both more electronegative than carbon or hydrogen. Their bond dipoles are not mirrored by the methyl end, so the isolated acid molecule is polar.

A USEFUL DISTINCTION

What to notice

The –COOH end is chemically and electrically different from CH3. Acetic acid also associates in dimers, which should not be confused with one-molecule geometry.

QUICK REFERENCE

Common questions about CH3COOH

  1. 01
    What does the Lewis structure of CH3COOH show?

    The connectivity is CH3–C(=O)–O–H. Both oxygen atoms have two lone pairs in the neutral Lewis drawing.

  2. 02
    What is the molecular geometry of CH3COOH?

    CH3COOH has a tetrahedral at methyl C; planar at carboxyl C molecular geometry. The 3D model shows representative bond angles of 111.9° and 109.8° and 110.6°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of CH3COOH?

    CH3COOH has an approximate molar mass of 60.05 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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