MOLECULAR POLARITYFIELD NOTE 103 / 175

Is Ethanethiol (C2H6S) polar or nonpolar?

Ethanethiol (C2H6S) is polar because the sulfur-bearing –SH end differs from its two-carbon hydrocarbon end.

THE ANSWERPolar.

Ethanethiol · tetrahedral at C; bent at S

FIGURE 01

The molecule in space

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STRUCTURE / 01
S ×1C ×2H ×6
HHSCCHHHH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why C2H6S is polar

Ethanethiol has a CH3–CH2–S–H chain. Sulfur keeps two lone pairs and makes a bent local arrangement with C and H. The sulfur-containing end and the hydrocarbon end have different electron distributions, giving a net dipole.

A USEFUL DISTINCTION

What to notice

Ethanethiol and dimethyl sulfide share the formula C2H6S. One has an S–H bond; the other puts sulfur between two methyl groups, so their Lewis structures must not be merged.

QUICK REFERENCE

Common questions about Ethanethiol (C2H6S)

  1. 01
    What does the Lewis structure of Ethanethiol (C2H6S) show?

    The connectivity is CH3–CH2–S–H. Sulfur has two single bonds and two lone pairs, and both carbon atoms have four bonds.

  2. 02
    What is the molecular geometry of Ethanethiol (C2H6S)?

    Ethanethiol (C2H6S) has a tetrahedral at C; bent at S molecular geometry. The 3D model shows representative bond angles of 96.5° and 110.6° and 108.8°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of Ethanethiol (C2H6S)?

    C2H6S has an approximate molar mass of 62.13 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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