MOLECULAR POLARITYFIELD NOTE 73 / 175

Is CH3CHO polar or nonpolar?

CH3CHO is polar because its carbonyl C=O bond dominates the molecule's charge distribution.

THE ANSWERPolar.

Acetaldehyde · tetrahedral at methyl C; trigonal planar at carbonyl C

FIGURE 01

The molecule in space

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STRUCTURE / 01
O ×1C ×2H ×4
HHOCCHH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why CH3CHO is polar

The aldehyde carbon is double-bonded to oxygen and single-bonded to H and the methyl group. Oxygen draws electron density through C=O, while the other substituents are not equivalent opposing oxygen bonds.

A USEFUL DISTINCTION

What to notice

One carbon in acetaldehyde is locally tetrahedral and the carbonyl carbon is locally planar. The polar C=O group determines the overall dipole.

QUICK REFERENCE

Common questions about CH3CHO

  1. 01
    What does the Lewis structure of CH3CHO show?

    The connectivity is CH3–C(=O)–H. Oxygen has two lone pairs; the carbonyl carbon makes a double bond and two single bonds.

  2. 02
    What is the molecular geometry of CH3CHO?

    CH3CHO has a tetrahedral at methyl C; trigonal planar at carbonyl C molecular geometry. The 3D model shows representative bond angles of 109.1° and 110.1° and 109.4°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of CH3CHO?

    CH3CHO has an approximate molar mass of 44.05 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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