MOLECULAR POLARITYFIELD NOTE 06 / 175

Is Acetamide (C2H5NO) polar or nonpolar?

Acetamide (C2H5NO) is polar because its carbonyl and amide groups create strongly unequal electron density.

THE ANSWERPolar.

Acetamide · trigonal planar at carbonyl C; tetrahedral at methyl C

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
O ×1N ×1C ×2H ×5
HHCCNOHHH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why C2H5NO is polar

Acetamide has the connectivity CH3–C(=O)–NH2. The carbonyl C=O bond is strongly polar, while the nitrogen lone pair interacts with the adjacent carbonyl system. These two heteroatom regions are not balanced by the methyl group.

A USEFUL DISTINCTION

What to notice

The amide nitrogen is closer to planar than an isolated amine nitrogen because its lone pair can delocalize toward the carbonyl. The model is one conformer of that linked group.

QUICK REFERENCE

Common questions about C2H5NO

  1. 01
    What does the Lewis structure of C2H5NO show?

    The neutral drawing is CH3–C(=O)–NH2. Oxygen has two lone pairs and nitrogen has one; the C–N bond has partial double-bond character through resonance.

  2. 02
    What is the molecular geometry of C2H5NO?

    C2H5NO has a trigonal planar at carbonyl C; tetrahedral at methyl C molecular geometry. The 3D model shows representative bond angles of 120.9° and 122.5° and 116.6°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of C2H5NO?

    C2H5NO has an approximate molar mass of 59.07 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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