MOLECULAR POLARITYFIELD NOTE 17 / 175

Is C2H3ClO polar or nonpolar?

Acetyl Chloride (C2H3ClO) is polar because its C=O and C–Cl bonds create an asymmetric acyl-chloride end.

THE ANSWERPolar.

Acetyl Chloride · trigonal planar at acyl C

FIGURE 01

The molecule in space

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STRUCTURE / 01
Cl ×1O ×1C ×2H ×3
HHCClCOH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why C2H3ClO is polar

Acetyl chloride is CH3–C(=O)–Cl. The planar carbonyl carbon bonds to oxygen, chlorine, and a methyl group, so its bond dipoles are not arranged as identical substituents.

A USEFUL DISTINCTION

What to notice

Compare acetyl chloride with acetaldehyde: replacing the aldehydic H with Cl changes the functional group, not just the spelling.

QUICK REFERENCE

Common questions about C2H3ClO

  1. 01
    What does the Lewis structure of C2H3ClO show?

    The structure is CH3–C(=O)–Cl. Oxygen has two lone pairs and chlorine has three.

  2. 02
    What is the molecular geometry of C2H3ClO?

    C2H3ClO has a trigonal planar at acyl C molecular geometry. The 3D model shows representative bond angles of 110° and 108.5° and 110.2°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of C2H3ClO?

    C2H3ClO has an approximate molar mass of 78.50 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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