MOLECULAR POLARITYFIELD NOTE 140 / 175

Is NH2OH polar or nonpolar?

NH2OH is polar because its connected N and O centers have lone pairs and unequal bond directions.

THE ANSWERPolar.

Hydroxylamine · pyramidal at N; bent at O

FIGURE 01

The molecule in space

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STRUCTURE / 01
O ×1N ×1H ×3
HONHH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why NH2OH is polar

Nitrogen bonds to two hydrogens and oxygen and keeps a lone pair; oxygen bonds to nitrogen and hydrogen and keeps two lone pairs. These local pyramidal and bent environments create an asymmetric charge distribution.

A USEFUL DISTINCTION

What to notice

The written formula NH2OH is useful because it reveals the N–O bond. Treating all three H atoms as attached to N would be the wrong connectivity.

QUICK REFERENCE

Common questions about NH2OH

  1. 01
    What does the Lewis structure of NH2OH show?

    The connectivity is H2N–O–H. N has one lone pair and O has two.

  2. 02
    What is the molecular geometry of NH2OH?

    NH2OH has a pyramidal at N; bent at O molecular geometry. The 3D model shows representative bond angles of 99.4° and 100.7° and 106.9°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of NH2OH?

    NH2OH has an approximate molar mass of 33.03 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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