MOLECULAR POLARITYFIELD NOTE 15 / 175

Is Bromobenzene (C6H5Br) polar or nonpolar?

Bromobenzene (C6H5Br) is polar because its single C–Br bond breaks the equivalent positions of benzene.

THE ANSWERPolar.

Bromobenzene · planar aromatic ring; trigonal planar at ring C

FIGURE 01

The molecule in space

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STRUCTURE / 01
Br ×1C ×6H ×5
CCCHHCCCHHHBr
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why C6H5Br is polar

One bromine replaces a hydrogen on the aromatic ring. Bromine's C–Br bond and the five C–H directions do not have matching dipole strengths, so the molecule retains a net dipole even though the ring is nearly planar.

A USEFUL DISTINCTION

What to notice

Fluorobenzene, chlorobenzene, and bromobenzene have the same one-substituent ring pattern. The halogen changes bond polarity, while the broken benzene symmetry is shared.

QUICK REFERENCE

Common questions about C6H5Br

  1. 01
    What does the Lewis structure of C6H5Br show?

    The structure is C6H5–Br with an aromatic six-carbon ring. A Kekulé drawing has three alternating C=C bonds; Br has three lone pairs.

  2. 02
    What is the molecular geometry of C6H5Br?

    C6H5Br has a planar aromatic ring; trigonal planar at ring C molecular geometry. The 3D model shows representative bond angles of 120°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of C6H5Br?

    C6H5Br has an approximate molar mass of 157.01 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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