MOLECULAR POLARITYFIELD NOTE 81 / 175

Is CH3NO2 polar or nonpolar?

Nitromethane (CH3NO2) is polar because its charged-resonance nitro group produces a strongly polar end.

THE ANSWERPolar.

Nitromethane · tetrahedral at methyl C; planar nitro N

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
O ×2N ×1C ×1H ×3
HHNCOOH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why CH3NO2 is polar

Nitromethane is a methyl group attached to –NO2. Its oxygen-rich nitro group carries substantial bond polarity and is not canceled by the CH3 group.

A USEFUL DISTINCTION

What to notice

Nitromethane and methyl nitrite share CH3NO2 but connect differently: C–N in nitromethane versus C–O in methyl nitrite.

QUICK REFERENCE

Common questions about CH3NO2

  1. 01
    What does the Lewis structure of CH3NO2 show?

    One Lewis contributor is CH3–N+(=O)–O−; the double-bonded oxygen and negative oxygen exchange by resonance.

  2. 02
    What is the molecular geometry of CH3NO2?

    CH3NO2 has a tetrahedral at methyl C; planar nitro N molecular geometry. The 3D model shows representative bond angles of 124.1° and 118.1° and 108.6°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of CH3NO2?

    CH3NO2 has an approximate molar mass of 61.04 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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