MOLECULAR POLARITYFIELD NOTE 120 / 175

Is HCONH2 polar or nonpolar?

HCONH2 is polar because the carbonyl and amide groups create a strong unequal charge distribution.

THE ANSWERPolar.

Formamide · approximately planar around C and N

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
O ×1N ×1C ×1H ×3
HHONCH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why HCONH2 is polar

The C=O bond draws electron density toward oxygen, while the nitrogen lone pair interacts with the carbonyl system. The H on carbon and the two N–H bonds do not create an equal opposing end.

A USEFUL DISTINCTION

What to notice

Amide resonance makes the C–N bond less like a freely rotating simple single bond. A local Lewis sketch is useful but does not capture all electron delocalization.

QUICK REFERENCE

Common questions about HCONH2

  1. 01
    What does the Lewis structure of HCONH2 show?

    The main connectivity is H–C(=O)–NH2. Oxygen has two lone pairs; nitrogen's lone pair participates in amide resonance.

  2. 02
    What is the molecular geometry of HCONH2?

    HCONH2 has a approximately planar around C and N molecular geometry. The 3D model shows representative bond angles of 121.3° and 117° and 126.3°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of HCONH2?

    HCONH2 has an approximate molar mass of 45.04 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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