MOLECULAR POLARITYFIELD NOTE 117 / 175

Is HBr polar or nonpolar?

HBr is polar because bromine pulls bonding electrons more strongly than hydrogen across their single bond.

THE ANSWERPolar.

Hydrogen Bromide · linear

FIGURE 01

The molecule in space

Drag to turn the molecule. A two-atom molecule has no bond angle.

STRUCTURE / 01
Br ×1H ×1
HBr
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why HBr is polar

In hydrogen bromide, bromine (2.96) is more electronegative than hydrogen (2.20), pulling the shared electrons toward itself. This creates a partial negative charge on bromine (δ−) and partial positive on hydrogen (δ+).

A USEFUL DISTINCTION

What to notice

With only one H–Br bond, there is no second bond dipole to cancel it. The charge distribution is unequal across the two atoms.

QUICK REFERENCE

Common questions about HBr

  1. 01
    What does the Lewis structure of HBr show?

    H and Br share one bond. Br has three lone pairs and H has none.

  2. 02
    What is the molecular geometry of HBr?

    HBr is a two-atom molecule, so its geometry is linear. A bond angle needs three atoms and is not defined here.

  3. 03
    What is the molar mass of HBr?

    HBr has an approximate molar mass of 80.91 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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