MOLECULAR POLARITYFIELD NOTE 97 / 175

Is COF2 polar or nonpolar?

COF2 is polar because one C=O bond and two C–F bonds do not balance in its planar three-bond arrangement.

THE ANSWERPolar.

Carbonyl Fluoride · trigonal planar

FIGURE 01

The molecule in space

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STRUCTURE / 01
F ×2O ×1C ×1
FFOC
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why COF2 is polar

Carbon has three bonding regions: a carbonyl oxygen and two fluorines. The two C–F contributions are symmetric with each other but are not an equal opposite to the C=O bond, so the net dipole survives.

A USEFUL DISTINCTION

What to notice

A trigonal planar label specifies approximately 120° directions, not identical bonds. COF2 differs from symmetric BF3 because its three arms are not alike.

QUICK REFERENCE

Common questions about COF2

  1. 01
    What does the Lewis structure of COF2 show?

    The common Lewis structure is F–C(=O)–F. Oxygen has two lone pairs and each fluorine has three.

  2. 02
    What is the molecular geometry of COF2?

    COF2 has a trigonal planar molecular geometry. The 3D model shows representative bond angles of 120.2° and 119.9°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of COF2?

    COF2 has an approximate molar mass of 66.01 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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