MOLECULAR POLARITYFIELD NOTE 54 / 175

Is C7H5N polar or nonpolar?

Benzonitrile (C7H5N) is polar because the strongly polarized terminal C≡N group gives the molecule a nitrogen-rich end.

THE ANSWERPolar.

Benzonitrile · linear at nitrile C; planar phenyl ring

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
N ×1C ×7H ×5
CCCCCHHNCCHHH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why C7H5N is polar

Benzonitrile has a phenyl ring bonded to a nitrile carbon. The C≡N bond is nearly linear with the ring attachment and adds a distinct electron-rich nitrogen terminus.

A USEFUL DISTINCTION

What to notice

The phenyl ring does not erase the nitrile dipole; compare benzonitrile with hydrocarbon toluene.

QUICK REFERENCE

Common questions about C7H5N

  1. 01
    What does the Lewis structure of C7H5N show?

    The connectivity is C6H5–C≡N. The nitrile carbon has one single and one triple bond; nitrogen has one lone pair.

  2. 02
    What is the molecular geometry of C7H5N?

    C7H5N has a linear at nitrile C; planar phenyl ring molecular geometry. The 3D model shows representative bond angles of 120° and 120.9°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of C7H5N?

    C7H5N has an approximate molar mass of 103.12 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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