MOLECULAR POLARITYFIELD NOTE 66 / 175

Is CCl4 polar or nonpolar?

CCl4 is a nonpolar molecule because its perfect tetrahedral geometry causes all four polar C–Cl bond dipoles to cancel completely.

THE ANSWERNonpolar.

Carbon Tetrachloride · tetrahedral

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
Cl ×4C ×1
ClClCClCl
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why CCl4 is nonpolar

Each C–Cl bond in carbon tetrachloride is polar since chlorine (3.16) is more electronegative than carbon (2.55).

A USEFUL DISTINCTION

What to notice

Carbon tetrachloride is a classic example of polar bonds canceling in three dimensions: all four chlorines occupy equivalent tetrahedral positions.

QUICK REFERENCE

Common questions about CCl4

  1. 01
    What does the Lewis structure of CCl4 show?

    C forms four single C–Cl bonds. Each Cl carries three lone pairs; the central carbon has no lone pairs.

  2. 02
    What is the molecular geometry of CCl4?

    CCl4 has a tetrahedral molecular geometry. The 3D model shows representative bond angles of 109.4°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of CCl4?

    CCl4 has an approximate molar mass of 153.81 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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