MOLECULAR POLARITYFIELD NOTE 95 / 175

Is CO2 polar or nonpolar?

CO2 is a nonpolar molecule because its linear geometry causes the two polar C=O bond dipoles to cancel exactly.

THE ANSWERNonpolar.

Carbon Dioxide · linear

FIGURE 01

The molecule in space

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STRUCTURE / 01
O ×2C ×1
OOC
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why CO2 is nonpolar

Although each C=O bond is polar (O is more electronegative than C), CO2 is linear with a 180° bond angle.

A USEFUL DISTINCTION

What to notice

CO2 is linear and nonpolar, but each C=O bond is polar. It is the two equal, opposite bond dipoles that cancel.

QUICK REFERENCE

Common questions about CO2

  1. 01
    What does the Lewis structure of CO2 show?

    The common structure is O=C=O. Carbon forms two double bonds, and each oxygen has two lone pairs.

  2. 02
    What is the molecular geometry of CO2?

    CO2 has a linear molecular geometry. The 3D model shows representative bond angles of 180°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of CO2?

    CO2 has an approximate molar mass of 44.01 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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