MOLECULAR POLARITYFIELD NOTE 167 / 175

Is SO3 polar or nonpolar?

SO3 is a nonpolar molecule because its trigonal planar shape causes the three polar S=O bond dipoles to cancel symmetrically.

THE ANSWERNonpolar.

Sulfur Trioxide · trigonal planar

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
S ×1O ×3
SOOO
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why SO3 is nonpolar

Sulfur trioxide has a trigonal planar structure with 120° bond angles and no lone pairs on sulfur.

A USEFUL DISTINCTION

What to notice

SO3 and SO2 contain polar S–O bonds, but their overall shapes differ. Three equal directions in a plane cancel in SO3.

QUICK REFERENCE

Common questions about SO3

  1. 01
    What does the Lewis structure of SO3 show?

    An expanded-octet Lewis sketch draws three S=O double bonds around S. Resonance and delocalization are more informative than treating one fixed drawing as unique.

  2. 02
    What is the molecular geometry of SO3?

    SO3 has a trigonal planar molecular geometry. The 3D model shows representative bond angles of 120°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of SO3?

    SO3 has an approximate molar mass of 80.06 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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