MOLECULAR POLARITYFIELD NOTE 85 / 175

Is CH4 polar or nonpolar?

CH4 is a nonpolar molecule because its perfect tetrahedral symmetry causes all four C–H bond dipoles to cancel completely.

THE ANSWERNonpolar.

Methane · tetrahedral

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
C ×1H ×4
HHCHH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why CH4 is nonpolar

Methane has a perfect tetrahedral shape with all four C–H bonds pointing symmetrically in different directions.

A USEFUL DISTINCTION

What to notice

The C–H bonds are arranged equivalently around carbon. Their vector sum is zero even if an individual bond has a slight charge imbalance.

QUICK REFERENCE

Common questions about CH4

  1. 01
    What does the Lewis structure of CH4 show?

    C forms four C–H single bonds and has no lone pairs. Each H shares one pair of electrons with carbon.

  2. 02
    What is the molecular geometry of CH4?

    CH4 has a tetrahedral molecular geometry. The 3D model shows representative bond angles of 109.5°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of CH4?

    CH4 has an approximate molar mass of 16.04 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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