MOLECULAR POLARITYFIELD NOTE 100 / 175

Is Cyanogen (C2N2) polar or nonpolar?

Cyanogen (C2N2) is nonpolar because its matching terminal nitrogen atoms lie at opposite ends of a straight molecule.

THE ANSWERNonpolar.

Cyanogen · linear N–C–C–N chain

FIGURE 01

The molecule in space

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STRUCTURE / 01
N ×2C ×2
NNCC
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why C2N2 is nonpolar

Cyanogen has the connectivity N≡C–C≡N. Both nitrile ends pull charge in equal but opposite directions along one line. The molecule therefore has no net permanent dipole despite the polar C≡N bonds.

A USEFUL DISTINCTION

What to notice

HCN and cyanogen both contain a C≡N group. HCN has unlike ends and is polar; cyanogen has matching N≡C ends and cancels its two bond contributions.

QUICK REFERENCE

Common questions about C2N2

  1. 01
    What does the Lewis structure of C2N2 show?

    The chain is :N≡C–C≡N:. Each nitrogen has one lone pair, the central carbons share a single bond, and each C–N connection is triple.

  2. 02
    What is the molecular geometry of C2N2?

    C2N2 has a linear N–C–C–N chain molecular geometry. The 3D model shows representative bond angles of 180°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of C2N2?

    C2N2 has an approximate molar mass of 52.04 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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