MOLECULAR POLARITYFIELD NOTE 68 / 175

Is CF4 polar or nonpolar?

CF4 is nonpolar because four identical C–F bond dipoles cancel in a symmetric tetrahedron.

THE ANSWERNonpolar.

Carbon Tetrafluoride · tetrahedral

FIGURE 01

The molecule in space

Drag to turn the molecule. Show angles to read the model geometry.

STRUCTURE / 01
F ×4C ×1
FFFCF
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why CF4 is nonpolar

Each C–F bond is strongly polar, yet all four fluorines occupy equivalent directions around carbon. The bond dipoles balance in three dimensions, leaving no permanent molecular dipole.

A USEFUL DISTINCTION

What to notice

CF4 illustrates why a molecule with very polar bonds can still be nonpolar. Symmetry concerns the whole three-dimensional arrangement.

QUICK REFERENCE

Common questions about CF4

  1. 01
    What does the Lewis structure of CF4 show?

    Carbon forms four C–F single bonds and has no lone pairs. Each fluorine has three lone pairs.

  2. 02
    What is the molecular geometry of CF4?

    CF4 has a tetrahedral molecular geometry. The 3D model shows representative bond angles of 109.5°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of CF4?

    CF4 has an approximate molar mass of 88.00 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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