MOLECULAR POLARITYFIELD NOTE 52 / 175

Is C6H6 polar or nonpolar?

C6H6 is nonpolar because its six equivalent carbon and hydrogen positions form a symmetric planar ring.

THE ANSWERNonpolar.

Benzene · planar hexagonal ring

FIGURE 01

The molecule in space

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STRUCTURE / 01
C ×6H ×6
CHCCCCHHHCHH
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01 / MODEL RECORDPubChem 3D coordinates. Atom sizes and bond thickness are illustrative.How model data is used ↗

THE REASONING

Why C6H6 is nonpolar

Benzene is a planar six-carbon ring with one hydrogen attached to each carbon. Its delocalized π electrons and equivalent positions preserve overall symmetry, so there is no permanent molecular dipole.

A USEFUL DISTINCTION

What to notice

Alternating single and double lines in a Lewis sketch are resonance representations. The real benzene ring does not contain three permanently distinct double bonds.

QUICK REFERENCE

Common questions about C6H6

  1. 01
    What does the Lewis structure of C6H6 show?

    The ring has six C atoms and six C–H bonds. Two alternating-double-bond drawings are resonance forms of the delocalized π system.

  2. 02
    What is the molecular geometry of C6H6?

    C6H6 has a planar hexagonal ring molecular geometry. The 3D model shows representative bond angles of 120°. These angles come from the displayed model coordinates.

  3. 03
    What is the molar mass of C6H6?

    C6H6 has an approximate molar mass of 78.11 g/mol, calculated from its formula using abridged standard atomic weights. Natural isotope variation can change the last digits.

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